n-Alkan-2-one distributions in a northeastern China peat core spanning the last 16 kyr     

Yanhong Zheng  Weijian Zhou  Xiaomin LiuChuanlun L. Zhang 《Organic Geochemistry》2011,42(1):25-30

Most research on long chain methyl ketones has focused on their origins and distributions. Their application in paleoclimate studies is less common than that of other n-alkyl lipids. The goal of this research was to explore this potential by studying n-alkan-2-ones from the Hani peat sequence in northeastern China. They were identified using gas chromatography-mass spectrometry (GC-MS) and showed a distribution ranging from C₁₉ to C₃₁ with a strong odd/even predominance. This type of distribution is considered to derive from Sphagum and microbial oxidation of n-alkanes. Comparison with climate sensitive indicators and macrofossil analysis shows that microbial oxidation of n-alkanes derived from higher plants was enhanced during the warm early Holocene period. This led us to develop three n-alkan-2-one proxies - C₂₇/ΣC_23-31 (C₂₇/HMW-KET), carbon preference index (CPI_H-KET) and average chain length (ACL_(27-31)-KET) - as possible indicators of paleoclimate in the peat-forming environment. These proxies, in combination with C₂₇n-alkane δD values and peat cellulose δ¹⁸O records, might allow examination of paleo-ecosystem behavior during climatic evolution in northeastern China over the past 16,000 yr.  相似文献   

Geochemistry of Palaeozoic marine petroleum from the Tarim Basin, NW China: Part 3. Thermal cracking of liquid hydrocarbons and gas washing as the major mechanisms for deep gas condensate accumulations   总被引：2，自引：0，他引：2  

Shuichang Zhang  Jin Su  Xiaomei Wang  Guangyou Zhu  Haijun YangKeyu Liu  Zhenxi Li 《Organic Geochemistry》2011,42(11):1394-1410

The Lunnan Lower Uplift in the Tarim Basin, NW China contains a composite petroleum system with mainly biodegraded heavy oil in the west, normal oil in the center and gas condensate in the east. Twenty-three gas samples and 37 oil samples taken from three major hydrocarbon bearing intervals in the Lunnan lower bulge were analyzed for their stable carbon isotopes and molecular biomarkers. On the basis of their isotopic compositions, biomarkers, especially diamondoids, and integrating the physical properties of the hydrocarbons including densities, GOR and PVT relationships, it has been concluded that the recently discovered deep (6500 m) eastern Lungu giant Ordovician gas condensate pool with an estimated reserve of 723 million bbl oil equivalent is a secondary hydrocarbon accumulation derived from the mixing of an early formed oil and a late formed gas. The extremely dry gases with a gas dryness of >0.98 were derived from thermal cracking of crude oils and charged to an existing oil reservoir causing extensive gas washing and secondary alteration. Compared with most of the hydrocarbons in the Lunnan area, the gas from the eastern Lungu gas condensate pool has a heavier carbon isotopic composition, higher dryness and a higher maturity level. The unique physical, chemical and isotopic compositions of the gas condensate are believed to be a direct result of gas flushing of an early formed eastern Lungu oil pool by a late formed dry gas from oil cracking. The eastern Lungu gas condensate pool is presently characterized by containing “dry gas, heavy oil, abundant aromatics and high wax”.  相似文献   

Geological, geochemical characteristics and isotope systematics of the Longqiao iron deposit in the Lu-Zong volcano-sedimentary basin, Middle-Lower Yangtze (Changjiang) River Valley, Eastern China   总被引：8，自引：0，他引：8  

Zhou Taofa  Wu Mingan  Fan Yu  Duan Chao  Yuan Feng  Zhang Lejun  Liu Jun  Qian Bing  Franco Pirajno  David R. Cooke 《Ore Geology Reviews》2011,43(1):154-169

The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling.  相似文献   

Pyrite–anhydrite–magnetite–pyroxene-type deposits and coexisting hydrothermal fluids in Mesozoic volcanic basins, Yangtze River Valley, China     

Ronghua Zhang  Xuetong Zhang  Shumin Hu 《Ore Geology Reviews》2011,43(1):315-332

Anhydrite–pyrite–magnetite–pyroxene–type deposits occur in the Mesozoic volcanic areas of the Middle–Lower Yangtze Valley in China. These deposits are hosted in alkaline basaltic rocks, and are generally accompanied by melanocratic and leucocratic alteration zones, both of which are characterized by a distinct vertical zonation pattern. Investigation of these zones indicates that the chemical compositions of solid solutions and polymorphs of various minerals vary spatially in the alteration profile, upwards from the lowest level, and outwards from the center.Here we report a case study on the Luohe deposit. In the melanocratic-alteration zone, the composition of magnetite (including trace elements Ti, V, Mg, Mn), pyroxene (Mg, Fe²⁺, Fe³⁺, Al₂O₃), plagioclase (An_xAb_{1 − x}), pyrite (Co, Ni) and apatite (F, CeO₂ + Y₂O₃ + La₂O₃) changes with depth. The isotherms of hydrothermal fluids determined from fluid inclusion data, including homogenization temperature and salinity, also vary with depth.Activity diagrams were constructed from mineral and isotherm analysis to estimate the chemical constraints on the alteration-mineral assemblages and the coexisting hydrothermal solutions for the Na₂O–K₂O–CaO–MgO–FeO–Fe₂O₃–A1₂O₃–SiO₂–H₂SO₄–H₂S–HCI–H₂O system at 350 to 600 °C and 500 bars (50 MPa), assuming that the major alteration mineral assemblages along the profile reflect the nature of the coexisting hydrothermal solutions. The activity diagrams adopted the major minerals as buffers to fix the activities of the aqueous species in the system, simulating the physicochemical conditions of the magnetite–anhydrite–pyroxene equilibrium and of solid solutions of diopside–hedenbergite, grossular–andradite and anorthite–albite found in the profile.This study provides an approach to modeling the chemical constraints of coexisting fluids in ore-alteration zones based on field observations.  相似文献   

塔里木盆地覆盖区寒武系生物地层研究新进展   总被引：2，自引：0，他引：2  

熊剑飞  余腾孝  曹自成  赵明  樊怀阳  武涛 《地层学杂志》2011,(4):419-430

全球有关寒武系生物地层的材料大都来自露头区,而鲜见于钻井材料。依据塔里木盆地中石化的11口探井及中石油的库南1井,报道寒武系生物地层研究方面取得的一些新进展：发现小壳化石、微古植物等15个门类的微体化石（小壳类及牙形类58属73种,微古植物29属30种）,其中软舌螺类Paragloborites,Circotheca,...  相似文献   

深圳大鹏半岛国家地质公园中生代火山地层的时代讨论     

梅村  唐跃林  张崧  康镇江  管福贞  龚淑云  李甘 《地层学杂志》2011,(4):454-462

深圳地区中生代火山地层分布区是我国东南沿海浙闽粤港火山活动带的一个重要组成部分,是我国沿海地区侏罗纪—白垩纪火山地层较有代表性地段,也是研究我国东南沿海侏罗纪—白垩纪火山活动的天然博物馆。近期通过野外观察,测制火山地层剖面,进行锆石同位素激光定年测试,对大鹏半岛国家地质公园中生代火山地层的时代提出新的认识,将原划分为上侏罗统高基坪群划分为早—中侏罗世塘厦组(181.8 Ma?)、中侏罗世吉岭湾组(165.8 Ma)、晚侏罗世梧桐山组(156.9~145.6 Ma)、晚侏罗世—早白垩世七娘山组(146.3~131.0 Ma)、早白垩世官草湖群等。  相似文献   

内蒙古乌拉特后旗查干德尔斯钼矿床地质特征及Re-Os测年   总被引：7，自引：1，他引：6  

蔡明海  彭振安  屈文俊  贺钟银  冯罡  张诗启  徐明  陈艳 《矿床地质》2011,30(3):377-384

查干德尔斯钼矿床是近年来在内蒙古西部中蒙边境地区新发现的一个具大型规模的隐伏矿床,辉钼矿化呈浸染状、团块状、细脉状分布在中细粒二长花岗岩中,具斑岩型矿床的特点.笔者在矿区成矿岩体、矿化和蚀变特征等初步研究的基础上,进行了辉钼矿Re-Os测年,获得模式年龄为(240.3±3.9)～(244.2±3.5)Ma,等时线年龄为...  相似文献   

Distribution of continental red paleosols and their forming mechanisms in the Late Cretaceous Yaojia Formation of the Songliao Basin, NE China     

Xuebin Du  Xinong Xie  Yongchao Lu  Jianye Ren  Shun ZhangPenglin Lang  Tao ChengMing Su  Cheng Zhang 《Cretaceous Research》2011,32(2):244-257

  相似文献   

碎屑锆石对班公湖地区晚侏罗世-早白垩世沉积物源的制约   总被引：2，自引：0，他引：2       下载免费PDF全文

樊帅权  史仁灯  丁林  张国凯 《地质科学》2011,(3):847-864

本文对班公湖地区中生代沙木罗组（J3—K1s）和日松组（J3r）地层的碎屑锆石进行了形态学及U-Pb年代学的研究。结果表明：锆石颗粒粒径约为100～150 μm,内部结构清晰,晶体为长柱状,自形程度较高,多数锆石不含暗色包体及浑圆形内核; 有些锆石颗粒有扇型分带结构。Th/U比值较大,多数大于0.1,均值约为0.86,说明岩浆的成因以锆石为主体,部分颗粒或晶体可能为变质成因; 锆石年龄主要分布在6个区间范围内： 1）180～100 Ma, 2）350～180 Ma, 3）600～450 Ma, 4）1100～600 Ma, 5）1800～1400 Ma, 6）2200～1800 Ma。锆石U-Pb年龄谱对应了羌塘地块经历的几次构造热事件,验证了晚侏罗世—早白垩世班公湖地区的物源主要来自其北部的羌塘地块。  相似文献   

海塔盆地优质储层发育特征及控制因素分析   总被引：2，自引：2，他引：0       下载免费PDF全文

张云峰  徐涵  肖岩岩  张玉鹏 《地质科学》2011,46(4):1017-1024

凝灰质砂岩是海塔盆地主要油气储集岩层,凝灰质含量随地层变老而增多,储层物性非均质性强,大量薄片等储层微观分析结果表明,凝灰质砂岩成分和结构成熟度较低,储层储集空间主要为溶蚀成因的次生孔隙,且次生孔隙比例随地层变老而增加.本文提出孔隙成因法,并根据该方法确定凝灰质砂岩优质储层物性下限的孔隙度为10％,渗透率为0.1×10...  相似文献